Scrub is a pass over all filesystem data and metadata and verifying the checksums. If a valid copy is available (replicated block group profiles) then the damaged one is repaired. All copies of the replicated profiles are validated.
Note
Scrub is not a filesystem checker (fsck) and does not verify nor repair structural damage in the filesystem. It really only checks checksums of data and tree blocks, it doesn’t ensure the content of tree blocks is valid and consistent. There’s some validation performed when metadata blocks are read from disk but it’s not extensive and cannot substitute full btrfs check run.